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废轮胎与减压渣油的低温共热解研究

晓清 胥(中南民族大学,中国)
成超 刘(中南民族大学,中国)
金林 李(中南民族大学,中国)

摘要

废旧轮胎与减压渣油因难降解且组分复杂,常规处置能效低、资源化不足。本文以60WT/40VR为研究对象,在无氧条件下开展低温催化共热解,系统考察不同温度制备Fe/C催化剂对三相产率、油品组分的影响。结果表明:加入催化剂后,360℃馏分降低、480℃馏分升高,而总油基本不变;其中Fe/C-700的总油收率可达≈40.0 wt%。GC-MS分析表明,D-柠檬烯含量由3.6%最高提升至28.7%。该研究阐明了铁基碳复合催化剂在WT×VR低温协同转化中的作用,为废弃物清洁高值化利用提供技术依据。

关键词

废轮胎热解;减压渣油热解;产物分布

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参考

Che, Y.; Hao, J.; Zhang, J.; Qiao, Y.; Li, D.; Tian, Y., Vacuum Residue Thermal Cracking: Product Yield Determination and Characterization Using Thermogravimetry–Fourier Transform Infrared Spectrometry and a Fluidized Bed Reactor. Energy Fuels 2018, 32 (2), 1348-1357.2. Han, W.; Han, D.; Chen, H., Pyrolysis of Waste Tires: A Review. Polymers 2023, 15 (7), 1604.3. Kusumi, R.; Kusumawati, M. B.; Borjigin, S.; Kumagai, S.; Yoshida, A.; Nakatsuka, Y.; Takasawa, R.; Toyooka, Y.; Yoshioka, T., Enhancement of liquid/gas production during co-pyrolysis of vacuum residue and plastics due to synergistic interactions. Scientific Reports 2024, 14 (1), 22856.4. Uçar, S.; Karagöz, S.; Yanik, J.; Saglam, M.; Yuksel, M., Copyrolysis of scrap tires with waste lubricant oil. Fuel Process. Technol. 2005, 87 (1), 53-58.5. Qu, B.; Zhang, Y.; Wang, T.; Li, A.; Wu, Z.; Ji, G. Dynamic Pyrolysis Characteristics, Kinetics and Products Analysis of Waste Tire Catalytic Pyrolysis with Ni/Fe-ZSM-5 Catalysts Using TG-IR-GC/MS Catalysts [Online], 2021.6. Kasar, P.; Ahmaruzzaman, M., Characterization of liquid products obtained from catalytic binary co-cracking of residual fuel oil with various waste plastics. Scientific Reports 2022, 12 (1), 10987.7. Liang, Z.; Jiang, Z.; Xue, Z.; Qiao, P.; Wu, W.; Jiang, Y.; Tang, X.; Chen, R.; Arif, M., Molecular structure and evolution mechanism of shale kerogen: Insights from thermal simulation and spectroscopic analysis. J. Anal. Appl. Pyrolysis 2024, 181, 106648.8. Januszewicz, K.; Kazimierski, P.; Kosakowski, W.; Lewandowski, W. M., Waste Tyres Pyrolysis for Obtaining Limonene. Materials 2020, 13 (6), 1359.9. Zhang, Y.; Cheng, S.; Ji, G.; Li, A., Refinement of limonene epoxides from the light distillate of tire pyrolysis oil via catalytic epoxidation. Separation and Purification Technology 2023, 319, 124068.图 3 轮胎和重油热解油的 GC-MSba



DOI: http://dx.doi.org/10.12345/zyyhbjz.v3i9.32333

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